Atmospheric CO2 has been reported to be on a rapid increase in recent times mainly due to the rising consumption of fossil fuel for anthropogenic activities. Currently the situation is that of the 25% fossil fuel consumption by the transportation sector, aviation sector consumes about 13% of transport fuel consumption, which is the second biggest sector after road transportation. Therefore, the applications of biofuels have been increased in aviation. The aim of this work is to investigate and compare biodiesel and its blends with syntactic kerosene. The pollutants of particulate emissions and their size distributions were analyzed. Jet A1 and blends of Jet A1 and biodiesel in volume ratios of 90:10 (B10), 80:20 (B20), 70:30 (B30), 50:50 (B50) and 30:70 (B70) mixed with 2.5% turbine lubricating oil were tested. The fuels were tested at three load conditions (throttle settings): Full power, 70% and idle condition. Scanning Mobility Particle Sizer has been used to determine the particulate size distribution and the number of concentration of diluted exhaust gases. The results showed that particulates from all throttle settings showed uni-modal distribution characteristics. Particulate number concentration of each fuel increases with the increase in throttle position. The increase in biodiesel ratio in biodiesel blend has also increased the particulate size concentration. More particulates were seen to be produced with Jet A1 and lower blends of biodiesel. The engine also produces a significantly higher number of particles at full power for all fuel types. Keywords: Biodiesel, Micro Gas Turbine Engine, Scanning Mobility Particle Sizer, waste cooking oil, pollutants.